Erik Swietlicki
Professor
Effective Density and Mixing State of Aerosol Particles in a Near-Traffic Urban Environment.
Author
Summary, in English
In urban environments, airborne particles are continuously emitted, followed by atmospheric aging. Also, particles emitted elsewhere, transported by winds, contribute to the urban aerosol. We studied the effective density (mass-mobility relationship) and mixing state with respect to the density of particles in central Copenhagen, in wintertime. The results are related to particle origin, morphology, and aging. Using a differential mobility analyzer-aerosol particle mass analyzer (DMA-APM), we determined that particles in the diameter range of 50-400 nm were of two groups: porous soot aggregates and more dense particles. Both groups were present at each size in varying proportions. Two types of temporal variability in the relative number fraction of the two groups were found: soot correlated with intense traffic in a diel pattern and dense particles increased during episodes with long-range transport from polluted continental areas. The effective density of each group was relatively stable over time, especially of the soot aggregates, which had effective densities similar to those observed in laboratory studies of fresh diesel exhaust emissions. When heated to 300 °C, the soot aggregate volatile mass fraction was ∼10%. For the dense particles, the volatile mass fraction varied from ∼80% to nearly 100%.
Department/s
- Nuclear physics
- Ergonomics and Aerosol Technology
- Solid State Physics
- MERGE: ModElling the Regional and Global Earth system
Publishing year
2014
Language
English
Pages
6300-6308
Publication/Series
Environmental Science & Technology
Volume
48
Issue
11
Full text
Document type
Journal article
Publisher
The American Chemical Society (ACS)
Topic
- Subatomic Physics
- Production Engineering, Human Work Science and Ergonomics
- Condensed Matter Physics
Status
Published
ISBN/ISSN/Other
- ISSN: 1520-5851