Javascript is not activated in your browser. This website needs javascript activated to work properly.
You are here

Structural Studies of 1,1-Dimethyl-2-oxy-1-silacyclohexane by Means of Matrix Isolation Infrared Absorption Spectroscopy

  • Justinas Ceponkus
  • M. Jonusas
  • C. P. Cotter
  • Milda Pucetaite
  • V Aleksa
  • G. A. Guirgis
  • Valdas Sablinskas
Publishing year: 2015
Language: English
Pages: 2721-2726
Publication/Series: Journal of Physical Chemistry A
Volume: 119
Issue: 11
Document type: Journal article
Publisher: The American Chemical Society (ACS)

Abstract english

Infrared spectra of gaseous, liquid, and matrix-isolated samples of newly synthesized 1,1-dimethyl-2-oxy-1-silacyclohexane were recorded. Raman spectra of 1,1-dimethyl-2-oxy-1-silacyclohexane in liquid and solid states were obtained in the temperature range from 170 to 340 K. Ab initio HF and DFT B3LYP calculations were performed in order to determine the possible conformations of 1,1-dimethyl-2-oxy-1-silacyclohexane and to make accurate assignment of the vibrational spectral bands. The study confirms the existence of only one chair-type conformer of 1,1-dimethyl-2-oxy-1-silacyclohexane.


  • ISSN: 1520-5215
Milda Pucetaite. Photo.
E-mail: milda [dot] pucetaite [at] cec [dot] lu [dot] se


Centre for Environmental and Climate Research (CEC)

+46 46 222 47 80


Ekologihuset, Sölvegatan 37, Lund


Centre for Environmental and Climate Research, CEC

Sölvegatan 37
223 62 Lund, Sweden

Visiting address
The Ecology Building, Sölvegatan 37, Lund

About this website