Your browser has javascript turned off or blocked. This will lead to some parts of our website to not work properly or at all. Turn on javascript for best performance.

The browser you are using is not supported by this website. All versions of Internet Explorer are no longer supported, either by us or Microsoft (read more here: https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Please use a modern browser to fully experience our website, such as the newest versions of Edge, Chrome, Firefox or Safari etc.

Per Persson. Photo.

Per Persson

Director

Per Persson. Photo.

Characterization of Iron and Organic Carbon Colloids in Boreal Rivers and Their Fate at High Salinity

Author

  • Simon David Herzog
  • Luigi Gentile
  • Ulf Olsson
  • Per Persson
  • Emma Sofia Kritzberg

Summary, in English

Riverine colloids are important carriers of macronutrients, trace metals, and pollutants into marine waters. The aim of the current study was to extend the understanding of iron (Fe) and organic carbon (OC) colloids in boreal rivers and their fate at higher salinities. X-ray absorbance spectroscopy (XAS) and dynamic light scattering (DLS) were combined to explore Fe speciation and colloidal characteristics such as size and surface charge and how these are affected at increasing salinity. XAS confirmed the presence of two Fe phases in the river waters—Fe-organic matter (OM) complexes and Fe(oxy)hydroxides. From DLS measurements on filtered and unfiltered samples, three particle size distributions were identified. The smallest particles (10–40 nm) were positively charged and suggested to consist of essentially bare Fe(oxy)hydroxide nanoparticles. The largest particles (300–900 nm) were dominated by Fe(oxy)hydroxides associated with chromophoric molecular matter. An intermediate size distribution (100–200 nm) with a negative surface charge was presumably dominated by OM and containing Fe-OM complexes. Increasing the salinity resulted in a removal of the smallest distribution. Unexpectedly, both the intermediate and largest size distributions were still detected at high salinity. The collective results suggest that Fe(oxy)hydroxides and Fe-OM complexes are both found across the wide size range studied and that colloidal size does not necessarily reflect either Fe speciation or stability toward salinity-induced aggregation. The findings further demonstrate that also particles beyond the typically studied <0.45-μm size range should be considered to fully understand the riverine transport and fate of macronutrients, trace metals, and pollutants.

Department/s

  • Aquatic Ecology
  • Centre for Environmental and Climate Science (CEC)
  • Division aquatic ecology
  • BECC - Biodiversity and Ecosystem services in a Changing Climate
  • Molecular Ecology and Evolution Lab
  • Physical Chemistry
  • MEMEG

Publishing year

2020-04-01

Language

English

Publication/Series

Journal of Geophysical Research - Biogeosciences

Volume

125

Issue

4

Document type

Journal article

Publisher

Wiley

Topic

  • Physical Chemistry

Keywords

  • DLS
  • Fe speciation
  • natural colloids
  • size distribution
  • XAS

Status

Published

Research group

  • Aquatic Ecology
  • Molecular Ecology and Evolution Lab

ISBN/ISSN/Other

  • ISSN: 2169-8953